Översikt

  • Allmänt

    • Short description of the course

      • Core concepts: Structure, bonding, synthesis, and characterization of solid state materials.
      • Core practical skills: Use of crystal structure databases, visualization of crystal structures, interpretation of phase diagrams, and phase identification with powder X-ray diffraction data.
      • Application of the above core concepts and skills to various main group compounds and transition metal compounds.

      Teacher: Antti Karttunen (antti.karttunen@aalto.fi).

    • Course information

    • Week 1: Crystal structure

    • Structure of crystalline materials. Symmetry.

    • Structural databases, visualization of crystal structures

    • Week 2: Bonding in solids

    • Electronegativity. Atomic/ionic radii. Description of crystal structures (coordination, close-packing, structure types).

    • Band theory. Band structures.

    • Week 3: Synthesis of solid-state materials

    • Phase diagrams and crystal growth

    • Solid state synthesis

    • Week 4: Characterization of solid-state materials

    • Miller indices. X-ray techniques. Phase identification by powder XRD. Microscopies.

    • Spectroscopies and thermal analysis.

    • Week 5: Main group compounds

    • Geochemistry and abundance of elements. Minerals and mineral databases.

    • Main group compounds (allotropes, Zintl phases)

    • Week 6: d-block metal compounds

    • d-electrons and Ligand Field Theory

    • Magnetism and d-block compounds

    • Week 7: Defects and doping

    • Defects and solid solutions

    • Semiconductors, doping, electrical properties